Oil-drop experiment was the first direct and
compelling measurement of the electric charge of a single electron. It was
performed originally in 1909 by the American physicist Robert A. Millikan. Using
a perfume atomizer, he sprayed tiny drops of oil into a transparent chamber. At
the top and bottom were metal plates hooked to a battery, making one positive
(red in animation) and the other negative (blue in animation). Since each
droplet picked up a slight charge of static electricity as it traveled through
the air, the speed of its motion could be controlled by altering the voltage on
the plates. When the space between the metal plates is ionized by radiation
(e.g., X rays), electrons from the air attach themselves to oil droplets,
causing them to acquire a negative charge. Millikan observed one drop after
another, varying the voltage and noting the effect. After many repetitions he
concluded that charge could only assume certain fixed values. The smallest of
these portions was none other than the charge of a single electron.